- 研究方向:
- 一、能量存储与转换材料
二、导电纤维及其传感特性
三、全生物降解复合材料
- 学习及工作经历:
- 2000年在中科院长春应用化学研究所获得理学博士学位；曾在中科院长春应用化学研究所国家电化学与光谱分析测试中心、高分子化学与物理国家实验室，复旦大学先进光学材料与器件国家实验室和香港科技大学物理系从事过研究工作；2006年加入东华大学材料科学与工程学院纤维材料改性国家重点实验室。已在SCI收录的知名期刊上发表研究论文三十余篇，编写专著两章；申请专利十一项。
- 已取得的主要研究成果：
- (1) 具有核壳结构的导电高分子、金属氧化物与碳纳米管复合体系的研究。特别注重高有序纳米结构和功能特性的调控和多功能集成。该复合体系在超级电容器、太阳能电池、光电纳米器件、传感器等方面具有潜在的应用前景。就聚苯胺/碳纳米管复合体系，作为超级电容器储能材料，其最大比电容量可达560F/g。具有核壳结构复合体系的综合性能明显优异。
(2) 高弹高导的导电纤维的研究。这种新型导电纤维除了新赋予的优异的导电性能以外，还保留着有机纤维基体原有的力学性能，特别是纤维的柔顺性和可编织性，可通过针织、机织编织成织物。这种导电纤维与织物除了具备传统的抗静电与电磁屏蔽功能特性外，还可用来制作纤维应力传感、气体传感、液体传感、光、热传感等多重响应传感器，并在金属离子吸附、催化去污和能量存储以及军事伪装等领域显示出巨大的应用潜力。如聚氨酯基的柔性导电纤维的电导率比常见的抗静电纤维高4～7个数量级。
(3) 生物可降解的固-固相变纳米纤维材料的研究。通过一种绿色途径将储能单元接枝到刚性骨架上，开发出一种新型生物可降解的纳米纤维储能材料，具有储能性能高与结构稳定的优点，在温度调节及蓄热保温等领域有着广泛的应用前景。
- 主要论文：
- 2008年以来发表的研究论文：
[1] Yi Zhou, Zong-Yi Qin, Li Li, Yu Zhang, Yu-Ling Wei, Ling-Feng Wang, Mei-Fang Zhu, Polyaniline/multi-walled carbon nanotube composites with core–shell structures as supercapacitor electrode materials, Electrochimica Acta 55: 3904–3908 (2010)
[2] Li Li, Zong-Yi Qin, Ling-Feng Wang, Hong-Jin Liu, Mei-Fang Zhu, Anchoring alpha-manganese oxide nanocrystallites on multi-walled carbon nanotubes as electrode materials for supercapacitor, J Nanopart Res 12: 2349–2353 (2010)
[3] Qing-Qing Fan, Zong-Yi Qin, Xia Liang, Li Li, Wen-Hua Wu, Mei-Fang Zhu, Reducing defects on multi-walled carbon nanotube surfaces induced by low-power ultrasonic-assisted hydrochloric acid treatment, Journal of Experimental Nanoscience, 5(4): 337–347 (2010)
[4] Guangzhao Zhai, Qingqing Fan, Yue Tang, Yu Zhang, Ding Pan, Zongyi Qin. Conductive composite films composed of polyaniline thin layers on microporous polyacrylonitrile surfaces. Thin Solid Films 519: 169–173 (2010)
[5] L. Li, Zong-Yi QIN, X. Liang, Q. Fan, Y. Lu, W. Wu, M. Zhu, Facile Fabrication of Uniform Core-Shell Structured Carbon Nanotube-Polyaniline Nanocomposites, J. Phys. Chem. C. 113: 5502–5507 (2009)
[6] Q. Liu, M. Zhu, W. Wu, Zong-Yi QIN, Reducing the formation of six-membered ring ester during thermal degradation of biodegradable PHBV to enhance its thermal stability, Polym. Degrad. Stab. 94: 18–24 (2009)
[7] L. Li, Zong-Yi QIN, Q. Fan, Y. Lu, M. Zhu, Y. Ding, Performance of hydrothermal fabricated manganese dioxide CNTs nanocomposites as electrodes material, Journal of Scientific Conference Proceedings, 1: 1–4 (2009)
[8] Y. Jiang, M. Zhu, B. Li, Y. Liu, Zong-Yi QIN, L. Chen, Y. Chen, Swelling Behavior of Poly(acrylamide)/Clay Nanocomposite Hydrogels in Acrylamide Aqueous Solution, J. Appl. Polym. Sci., 112: 353–358 (2009)
[9] K.P. Shiu, Zong-Yi QIN, Z. Yang, Relaxation times and energy barriers of rubbing-induced birefringence in glass-forming polymers, Eur. Phys. J. E. 27: 413–420 (2008)
[10] C.C. Wong, Zong-Yi QIN, Z. Yang, The absence of physical-aging effects on the surface relaxations of rubbed polystyrene, Eur. Phys. J. E. 25: 291–298 (2008)
[11] C. Ma, W. Du, H. Chen, Z. Liu, Zong-Yi QIN, D. Pan, Influences of Nonsolvent and Temperature on Critical Viscoelastic Behaviors of Ternary Polyacrylonitrile Solutions Around the Sol-Gel Threshold, J. Polym. Sci. Part B: Polym. Phys. 46: 2637–2643 (2008)
[12] C. Ma, W. Yan, L. Zhang, Zong-Yi QIN, P. Ding, Rheological behavior during thermotropic gelation of polyacrylonitrile concentrated solutions, J. Cent. South Univ. Technol. 15(s1): 122-125 (2008)
会议论文：
[1] Y Zhang, X Ren, K Zhang, Zong-Yi QIN, Influence of shell layer thickness on electrochemical process for polyaniline and polypyrrole coaxial nanofibers as supercapacitor electrode materials, The 9th China International Nanoscience and Technology Symposium, 2010, Xi'an.
[2] HY Yu, Z Zhou, SS Shan, N. Guo, MF Zhu, Zong-Yi QIN. Electrospun solid-solid phase change nanofibers of poly(ethylene glycol) grafted onto the surface of cellulose nanocrystals. The 9th China International Nanoscience and Technology Symposium, 2010, Xi'an.
[3] Z Zhou, HY Yu, Zong-Yi QIN. Study on the Preparation and Properties of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)(PHBV)/Microcrystalline Cellulose and PHBV/Cellulose Nanocrystal Composites. The 9th China International Nanoscience and Technology Symposium, 2010, Xi'an.
[4] 范青青，张晓琳，丁永生，秦宗益，新型聚氨酯基导电纤维与织物研制及应用探讨，第十一届新型化纤原料在针织及其他相关行业应用技术研讨会，2010，郑州。
[5] Q Fan, Zong-Yi Qin, L Chen, J Gong, Y Tang, M Zhu, Preparation and sensing properties of novel polyurethane-carbon nanotube composite fibers, 10th European Symposium on Polymer Blends, 2010, Dresden, Germany.
[6] L. Wang, Zong-Yi QIN, L. Li, Y. Zhang, M. Zhu, Novel ternary composite consisting of multi-wallled carbon nanotubes and manganese dioxide nanorods dispersed in polyaniline matrix as supercapacitve material, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.
[7] Y. Zhou, Zong-Yi QIN, H. Liu, Y. Wei, L. LI, M. Zhu, Conductive Polymer/ Carbon Nanotubes Nanocomposites with Core-Shell Structures: Preparation and Properties, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.
[8] Y. Zhang, Zong-Yi QIN, Y. Wei, Y. Zhou, J. Ni, M. Zhu, Core-shell Nanostructured Polyaniline/Polypyrrole Composites as Electrode Materials for Supercapacitors, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.
[9] Q. Fan, Zong-Yi QIN, C. Zhao, J. Gong, M. Zhu, L. Li, Y. Ding, Evaluation temperature and strain sensing properties of electrically conductive elastic fibres, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.
[10] H. Liu, Zong-Yi QIN, Y. Zhou, L. Li, M. Zhu, Effect of Core-Shell Heterostructure on the Optical and Electrochemical Properties for Poly(p-phenylenevinylene) Wrapped Multi-walled Carbon Nanotubes, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.
[11] G. Zhai, Zong-Yi QIN, H. Li, H. Chen, D. Pan, Flexible conducting polyaniline/polyacrylonitrile composite films, International Conference on Advanced Fibers and Polymer materials, ICAFPM, 2009, Shanghai.
[12] L.Li, Zong-Yi Qin, Q. Fan, Y. Lu, M. Zhu, Y. Ding, Performance of hydrothermal fabricated manganese dioxide CNTs nanocomposites as electrodes material, 7th China international conference on nanoscience and technology, 2008，Wuhan, China
[13] 范青青，秦宗益，朱美芳，李龙飞，丁永生，高电导与高弹性碳纳米管表面复合聚氨酯导电纤维，2008 年上海纳米科技与产业发展研讨会，上海.
[14] 周毅，秦宗益，朱美芳，聚苯胺/多壁碳纳米管核壳结构中的聚苯胺掺杂效应，2008 年上海纳米科技与产业发展研讨会，上海。
[15] 王凌凤，秦宗益，李立，朱美芳，采用水热法合成MnO2纳米棒/多壁纳米管复合材料及其超电容特性研究, 2008 年上海纳米科技与产业发展研讨会，上海。
[16] 魏玉玲，秦宗益，陆亚清，朱美芳，界面聚合制备聚苯胺纳米纤维，2008 年上海纳米科技与产业发展研讨会，上海。
[16] 钮晓鸣，放大看纳米――2008 年上海纳米科技与产业发展研讨会论文选, 魏玉玲，秦宗益，陆亚清，朱美芳, 界面聚合制备聚苯胺纳米纤维，上海大学出版社(2009)
- 授权的专利：
- [1] 秦宗益，范青青，武永淘，张晓琳，蔡雅萌，一种弹性导电复合纤维及其制备方法，申请号：201110009585.X
[2] 秦宗益，王凌凤，唐月，蔡雅萌，骆洁妮，一种瓣状二氧化锰纳米晶包覆碳纳米管复合电极材料的制备方法，申请号：201010256458.5
[3] 秦宗益，张瑜，郭娜，张晓琳，张开永，任晓燕，田菲，核壳结构的聚苯胺/聚吡咯复合纳米纤维电极材料的制备，申请号：201010228217.X
[4] 秦宗益，范青青，李虎敏，魏玉玲，唐月，朱美芳, 一种柔性碳纳米管-聚氨酯红外敏感薄膜及其制备方法，申请号：200910199519.6
[5] 秦宗益，余厚咏，张天鹭，刘彦男，生物可降解的固-固相变纳米纤维或纤维膜的制备方法，申请号：201010513771.2
[6] 秦宗益，潘鼎，马彩霞，翟光照，范青青，陈惠芳，刘占莲，无皮芯结构聚丙烯腈基碳纤维原丝的凝胶纺丝原液及其制备, 申请号： 200910200222.7
[7] 秦宗益，范青青，朱美芳，刘庆生，魏玉玲，翟光照，丁永生, 具有高导电率与高弹性及应力传感性能的复合纤维及其制备方法，授权号：CN 200910046590.0
[8] 秦宗益，李立，朱美芳，范青青，魏玉玲，周毅，王凌凤，有核壳结构碳纳米管/导电高分子纳米杂化电极材料制备，申请号：200810207241.8
[9] 秦宗益，朱美芳，刘庆生，翟光照，李虎敏，陈龙，陈彦模，一种原位合成聚羟基脂肪酸酯嵌段共聚物的方法，申请号：200810207404.2
[10] 刘庆生，秦宗益，朱美芳，梁 霞，吴文华，陈龙，陈彦模，一种高热稳定性聚羟基脂肪酸酯的制备方法，授权号：CN 101148501B
- 近几年承担的科研项目：
- 主持承担了上海市科委浦江人才计划“基于导电高分子纳米纤维网络的光伏材料设计及智能服装柔性能源的研发”，上海市科委“创新行动计划”项目重大基础项目子课题“高性能PANCF纺丝原液热力学及流变行为研究”，上海市科委重点基础项目“自增强型资源可再生生物聚酯纤维的化学设计与梯度结构调控”和教育部高等学校科技创新工程重大项目培育资金“电子信息纤维材料及其智能服装的工程化研究”等项目。曾主持过一项国家自然科学基金项目和一项国家博士后研究基金项目，并作为研究骨干参加过多项国家自然科学基金项目。
- 国际交流与合作：
- 与香港科技大学物理系杨志宇教授(Jason Yang)合作开展“高分子超薄膜的物理性质”工作。
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